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Structural Studies on Methylated Starch Granules
Author(s) -
Vliegenthart Johannes F. G.,
van der Burgt Yuri E. M.,
Bergsma Jack,
Bleeker Ido P.,
Mijland Paul J. H. C.,
Kamerling Johannis P.
Publication year - 2000
Publication title -
starch ‐ stärke
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.62
H-Index - 82
eISSN - 1521-379X
pISSN - 0038-9056
DOI - 10.1002/(sici)1521-379x(200004)52:2/3<40::aid-star40>3.0.co;2-g
Subject(s) - amylopectin , amylose , starch , chemistry , polysaccharide , potato starch , chromatography , aqueous suspension , aqueous solution , organic chemistry
Granules of potato starch and amylopectin potato starch were methylated in aqueous alkaline suspension. Here, an overview is given of all structural aspects that have been studied with respect to the determination of the location of the substituents. Methods, which are generally applicable, were developed for the separation of different areas of derivatised starch granules, followed by determination of the substitution level. For methylated starch granules it was found that methyl groups are predominantly present in branched regions and amorphous domains, and that amylose is higher substituted than amylopectin. No differences were found between substitution levels of granules of various sizes, nor radially across the granules.