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Preparation, Structure, and Redox Reactions of Nine‐Membered Cyclic Peroxides: A Novel Electrochromic System Undergoing Reversible Extrusion and Trapping of O 2
Author(s) -
Suzuki Takanori,
Nishida Junichi,
Ohkita Masakazu,
Tsuji Takashi
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000515)39:10<1804::aid-anie1804>3.0.co;2-3
Subject(s) - electrochromism , redox , chemistry , deoxygenation , electrochemistry , orange (colour) , extrusion , ion , trapping , photochemistry , combinatorial chemistry , polymer chemistry , organic chemistry , materials science , electrode , catalysis , ecology , metallurgy , biology , food science
The hitherto unknown 1,2,6‐tricyclononane derivatives 1 (X=O, S) were readily obtained upon the electrochemical 2 electron reduction of 2 2+ in air (see scheme). Oxidative deoxygenation of the colorless peroxides 1 regenerates the orange 2 2+ ions.