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Giant Porphyrinoids: From Figure Eights to Nanomolecular Cavities
Author(s) -
Lash Timothy D.
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000515)39:10<1763::aid-anie1763>3.0.co;2-3
Subject(s) - conjugated system , chirality (physics) , pyrrole , annulene , metal ions in aqueous solution , chemistry , metal , combinatorial chemistry , stereochemistry , computational chemistry , organic chemistry , physics , quantum mechanics , nambu–jona lasinio model , quark , polymer , chiral symmetry breaking
Increasingly expanded porphyrinoids (example shown) are provided by new synthetic methods. These nonaromatic systems, which contain up to 16 conjugated pyrrole subunits, exhibit novel metal coordination chemistry, chirality, and anion binding characteristics.