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Thirty Electrons “Trapped” in a Spherical Matrix: A Molybdenum Oxide‐Based Nanostructured Keplerate Reduced by 36 Electrons
Author(s) -
Müller Achim,
Shah Syed Qaiser Nazir,
Bögge Hartmut,
Schmidtmann Marc,
Kögerler Paul,
Hauptfleisch Björn,
Leiding Stefan,
Wittler Kai
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000502)39:9<1614::aid-anie1614>3.0.co;2-9
Subject(s) - molybdenum , electron , materials science , oxide , matrix (chemical analysis) , molybdenum oxide , nanotechnology , atomic physics , physics , nuclear physics , metallurgy , composite material
Thirty electrons are frozen on the O = Mo(H 2 O) groups which function as spacer units between the {(Mo)Mo 5 } building units of the giant {Mo 102 } sphere 1 (the picture shows a wireframe representation in which the spacer units are represented as a darker shade).