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6 Li and 15 N NMR Data as a Probe for the Influence of Solvent and Intramolecular Solvation on the Solution‐State Structures of Chiral Lithium Amides
Author(s) -
Arvidsson Per I.,
Davidsson Öjvind
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000417)39:8<1467::aid-anie1467>3.0.co;2-i
Subject(s) - solvation , chemistry , intramolecular force , lithium (medication) , solvent , isotopes of lithium , solvent effects , computational chemistry , stereochemistry , organic chemistry , ion , medicine , ion exchange , endocrinology
Truly diverse aggregation and coordination abilities are observed for the chiral lithium amides 1 and 2 ! Symmetrically and unsymmetrically solvated dimers as well as cyclic trimers (see picture) are formed depending on the solvent and the stereochemical composition of the aggregate.