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Formation of Rearranged Grignard Reagents by Carbenoid‐C‐H Insertion
Author(s) -
Hoffmann Reinhard W.,
Knopff Oliver,
Kusche Andreas
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000417)39:8<1462::aid-anie1462>3.0.co;2-b
Subject(s) - carbenoid , grignard reagent , reagent , insertion reaction , grignard reaction , chemistry , combinatorial chemistry , organic chemistry , catalysis , rhodium
Grignard chemistry? —That is all known for more than 100 years! Thus, it is truely unexpected when a new Grignard reaction comes to light: a carbenoid C−H insertion into the α ‐C−H bond of a Grignard reagent [Eq. (1)].