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Facile and Clean Oxidation of Alcohols in Water Using Hypervalent Iodine( III ) Reagents
Author(s) -
Tohma Hirofumi,
Takizawa Shinobu,
Maegawa Tomohiro,
Kita Yasuyuki
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000403)39:7<1306::aid-anie1306>3.0.co;2-j
Subject(s) - hypervalent molecule , reagent , iodine , chemistry , benzene , catalysis , alcohol oxidation , organic chemistry , inorganic chemistry , combinatorial chemistry
An environmentally benign oxidation of alcohols in water using iodosobenzene (PhI=O) or a polymer‐supported (diacetoxyiodo)benzene (PSDIB) with KBr has been achieved (see scheme). This method results in the catalytic activation of a variety of sluggishly reactive and/or sparsely soluble hypervalent iodine reagents in water under neutral conditions.