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Crystal Engineering of Metalloporphyrin Zeolite Analogues
Author(s) -
DiskinPosner Yael,
Dahal Sanjay,
Goldberg Israel
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000403)39:7<1288::aid-anie1288>3.0.co;2-y
Subject(s) - zeolite , crystal engineering , supramolecular chemistry , crystal (programming language) , chemistry , materials science , crystal structure , crystallography , organic chemistry , catalysis , computer science , programming language
A uniquely structured molecular solid composed of pillared bilayers of metalloporphyrin building blocks has been formulated. It consists of a single three‐dimensional multicomponent supramolecular framework, resembling a zeolite, which accounts for only 42 % of the crystal volume (see picture). The spacious, open galleries between the pillars are readily accessible to other guest compounds.