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Crossed Condensation of Two Different Hydrosulfido‐Bridged Dinuclear Complexes: Structures and Reactivities of TiRu 3 S 4 Cubane‐Type Sulfido Clusters
Author(s) -
Kabashima Shinichiro,
Kuwata Shigeki,
Ueno Keiji,
Shiro Motoo,
Hidai Masanobu
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000317)39:6<1128::aid-anie1128>3.0.co;2-6
Subject(s) - cluster (spacecraft) , cubane , condensation , chemistry , crystallography , cube (algebra) , type (biology) , stereochemistry , crystal structure , physics , geometry , geology , paleontology , computer science , programming language , thermodynamics , mathematics
A cube‐shaped cluster , TiRu 3 S 4 , is derived from the selective combination of hetero‐ and homodinuclear fragments TiRuS 2 and Ru 2 S 2 , respectively (see scheme). The clusters exhibit a fluxional, temperature‐dependant behavior, ascribed to the proximity of Ru centers. [Ru]=Cp*Ru, [Ti]=CpTi.