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New Building Blocks for the Design of Oligonuclear Copper Complexes Based on Amino Carbohydrates
Author(s) -
Wegner Rainer,
Gottschaldt Michael,
Görls Helmer,
Jäger ErnstG.,
Klemm Dieter
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000204)39:3<595::aid-anie595>3.0.co;2-c
Subject(s) - copper , chemistry , catechol , stereochemistry , coupling (piping) , crystallography , combinatorial chemistry , biochemistry , materials science , organic chemistry , metallurgy
Remarkably high magnetic coupling and O 2 ‐activation ability analogous to that of catechol oxidase are characteristics of the first structurally defined, low‐symmetry oligonuclear copper complexes of tridentate β ‐oxoenamine ligands based on amino carbohydrates (the structure of a bis(acetylbutenonylaminoglucosidato)bis( μ ‐acetato)tricopper( II ) complex is shown).