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Molecular Dispersion of Chains in the Mixed‐Valence Complexes [M(en) 2 ][MCl 2 (en) 2 ] (M: Pt, Pd, Ni) and Anionic Amphiphiles in Organic Media
Author(s) -
Kimizuka Nobuo,
Lee Sang Ho,
Kunitake Toyoki
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000117)39:2<389::aid-anie389>3.0.co;2-2
Subject(s) - thermochromism , amphiphile , dissociation (chemistry) , valence (chemistry) , supramolecular chemistry , chemistry , solubilization , crystallography , molecule , organic chemistry , copolymer , polymer , biochemistry
A way to prepare molecular electronic wires in organic media is the solubilization of one‐dimensional mixed‐valence complexes with varied metal species through the formation of amphiphilic supramolecular assemblies (see picture). Dissociation and reassembly of the complex was detected as thermochromism in the intervalence (M II →M IV ) absorption bands.