Premium
Zirconium – Phosphorus Chemistry: Strategies in Syntheses, Reactivity, Catalysis, and Utility
Author(s) -
Stephan Douglas W.
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000117)39:2<314::aid-anie314>3.0.co;2-d
Subject(s) - reactivity (psychology) , chemistry , substituent , organometallic chemistry , catalysis , zirconium , organic chemistry , stoichiometry , phosphorus , combinatorial chemistry , medicine , alternative medicine , pathology
Dramatic developments have taken place over the last few years in the chemistry of complexes containing Zr−P bonds and their utilization in organophosphorus chemistry. This review discusses the synthesis and reactivity of compounds containing Zr−P single and double bonds, phosphazirconacycles, and Zr complexes of substituent‐free phosphorus. Applications in both stoichiometric and catalytic syntheses provide access to a variety of novel organophosphorus compounds and illustrate the potential of the organometallic approach to the synthesis of main group compounds.