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A Two‐Step Spin Crossover in [(TPA)Fe III (cat)]BPh 4
Author(s) -
Simaan A. Jalila,
Boillot MarieLaure,
Rivière Eric,
Boussac Alain,
Girerd JeanJacques
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000103)39:1<196::aid-anie196>3.0.co;2-w
Subject(s) - spin crossover , crossover , spin (aerodynamics) , materials science , magnetic susceptibility , condensed matter physics , chemistry , physics , thermodynamics , computer science , artificial intelligence
Measurement of magnetic susceptibility with temperature of a powdered iron( III ) catecholate complex clearly indicated a two‐step spin‐crossover process S =½↔ S =5/2. The picture shows the plot of χ M T against temperature.