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A Facile Route to Group 13 Difluorodiorganometalates: [ n Bu 4 N][R 2 MF 2 ] (M=Al, Ga, In)
Author(s) -
Roesky Herbert W.,
Stasch Andreas,
Hatop Hagen,
Rennekamp Carsten,
H. Hamilton David,
Noltemeyer Mathias,
Schmidt HansGeorg
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000103)39:1<171::aid-anie171>3.0.co;2-n
Subject(s) - alkyl , indium , gallium , group (periodic table) , chemistry , main group element , tetra , difluoride , polymer chemistry , materials science , combinatorial chemistry , inorganic chemistry , organic chemistry , medicinal chemistry , transition metal , catalysis
A facile synthesis utilizing tetra‐ n ‐butylammonium hydrogen difluoride and Group 13 alkyl compounds leads to the soluble salts 1 – 4 . Compound 1 is the smallest difluoro‐diorganoaluminate so far characterized. The corresponding gallium and indium derivatives 3 and 4 are not sensitive to moisture.