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Thermochemical Data of Organic Ions Obtained from Investigations in the More or Less “Diluted” Gas Phase
Author(s) -
Kuck Dietmar
Publication year - 2000
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(20000103)39:1<125::aid-anie125>3.0.co;2-r
Subject(s) - boranes , gas phase , chemistry , thermochemistry , ion , alpha (finance) , standard enthalpy of formation , proton , phase (matter) , inorganic chemistry , organic chemistry , physics , nuclear physics , medicine , construct validity , nursing , patient satisfaction , boron
How is a proton bound to an arene , how mobile is it in such a complex, and how much energy is required to remove it—these questions have been of fundamental interest in physical organic chemistry for half a century. The experimental determination of quantitative thermochemical data of organic elementary processes in the gas phase is discussed for recent examples, such as the α ‐acidification of tertiary amines by complexation with boranes (see reaction) and the “local” C α −H acidities of α , α , α ‐trifluoromethylbenzene and higher analogues.