Premium
Micropore Decoration with Bidentate Lewis Acids: Spontaneous Assembly of 1,2‐Bis(chloromercurio)tetrafluorobenzene
Author(s) -
Tschinkl Martin,
Schier Annette,
Riede Jürgen,
Gabbaï François P.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19991203)38:23<3547::aid-anie3547>3.0.co;2-p
Subject(s) - microporous material , chemistry , molecule , lewis acids and bases , denticity , dimethyl sulfoxide , sulfoxide , polymer chemistry , organic chemistry , crystal structure , catalysis
Dimethyl sulfoxide templates the assembly of 1,2‐bis(chloromercurio)tetrafluorobenzene ( 1 ) into an internally Lewis acidic microporous solid of composition 1 ⋅(DMSO) 3 ( 2 ). The channels of 2 contain both chelated and solvate DMSO molecules (omitted in the drawing for clarity), which can be partly exchanged with water molecules. The hydration–dehydration of the resulting compound is reversible.