Premium
Interpenetrated and Noninterpenetrated Three‐Dimensional Networks in the Polymeric Species Ag(tta) and 2 Ag(tta)⋅AgNO 3 (tta=tetrazolate): The First Examples of the μ 4 ‐ η 1 : η 1 : η 1 : η 1 Bonding Mode for Tetrazolate
Author(s) -
Carlucci Lucia,
Ciani Gianfranco,
Proserpio Davide M.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19991203)38:23<3488::aid-anie3488>3.0.co;2-h
Subject(s) - cationic polymerization , salt (chemistry) , chemistry , crystallography , metal organic framework , inorganic chemistry , polymer chemistry , adsorption
A twofold interpenetrated neutral three‐dimensional network with rectangular channels (left) and a noninterpenetrated three‐dimensional cationic framework (right) are the stuctural motifs observed in the simple salt Ag(tta) and in the double salt 2 Ag(tta)⋅AgNO 3 , respectively. These compounds exhibit the first examples of the μ 4 ‐ η 1 : η 1 : η 1 : η 1 bonding mode for tetrazolate (tta).