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Treatment of Naphthols with B(C 6 F 5 ) 3 : Formation and Characterization of the Lewis Acid Adducts of Their Keto Isomers
Author(s) -
Vagedes Dominik,
Fröhlich Roland,
Erker Gerhard
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19991115)38:22<3362::aid-anie3362>3.0.co;2-n
Subject(s) - adduct , tautomer , lewis acids and bases , chemistry , medicinal chemistry , characterization (materials science) , stereochemistry , organic chemistry , catalysis , nanotechnology , materials science
With the strong Lewis acid B(C 6 F 5 ) 3 , the keto tautomers from a variety of naphthol derivatives are obtained (e.g. α ‐naphthol, see scheme). The adducts of the tautomers were characterized by X‐ray structure analysis, and the first attempts at hydrozirconation of the adducts were made.