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Organotitanium Fluorides as Matrices for Trapping Molecular ZnF 2 and MeZnF
Author(s) -
Yu Peihua,
Müller Peter,
Roesky Herbert W.,
Noltemeyer Mathias,
Demsar Alojz,
Usón Isabel
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19991115)38:22<3319::aid-anie3319>3.0.co;2-s
Subject(s) - adduct , trapping , chemistry , molar ratio , crystallography , metal , crystal (programming language) , transition metal , catalysis , organic chemistry , biology , computer science , ecology , programming language
Trapped as molecular solids , the transition metal fluorides ZnF 2 and MeZnF—the latter isolated for the first time—exist as adducts in [(Cp*TiF 3 ) 8 (ZnF 2 ) 3 ] ( 1 ) and [(Cp*TiF 3 ) 4 (MeZnF) 2 ] ( 2 ), respectively. Compounds 1 and 2 were obtained in reactions of [Cp*TiF 3 ] (Cp*=C 5 Me 5 ) with ZnMe 2 and Me 3 SnF in various molar ratios. The single‐crystal structure of 1 is shown here; the unlabeled circles are F atoms.