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Solid‐State Coordination Chemistry: The Self‐Assembly of Microporous Organic–Inorganic Hybrid Frameworks Constructed from Tetrapyridylporphyrin and Bimetallic Oxide Chains or Oxide Clusters
Author(s) -
Hagrman Douglas,
Hagrman Pamela J.,
Zubieta Jon
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19991102)38:21<3165::aid-anie3165>3.0.co;2-o
Subject(s) - bimetallic strip , oxide , microporous material , cationic polymerization , chemistry , cluster (spacecraft) , hydrothermal circulation , metal organic framework , porphyrin , inorganic chemistry , yield (engineering) , supramolecular chemistry , hybrid material , metal , chemical engineering , polymer chemistry , materials science , crystallography , photochemistry , organic chemistry , crystal structure , adsorption , metallurgy , computer science , programming language , engineering
The hydrothermal reactions of MoO 3 , tetrapyridylporphyrin (tpypor), water, and the appropriate M II precursor yield the first examples of three‐dimensional framework materials constructed from metal oxide and porphyrin subunits. The picture shows a section of [{Fe(tpypor)} 3 Fe(Mo 6 O 19 ) 2 ]⋅ x H 2 O with the [Fe 8 (tpypor) 6 ] 8+ building block of the cationic framework and the entrained {Mo 6 O 19 } 2− cluster.