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Stable Polymer‐Bound Iodine Azide
Author(s) -
Kirschning Andreas,
Monenschein Holger,
Schmeck Carsten
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990903)38:17<2594::aid-anie2594>3.0.co;2-u
Subject(s) - iodate , reagent , azide , iodine , halogenation , polymer , chemistry , combinatorial chemistry , sodium azide , polymer chemistry , organic chemistry
1,2‐Azido‐iodination of a wide range of alkenes under very mild conditions can be achieved by using a novel iodate( I ) reagent, a stable and storable polymer‐bound iodine azide, which is available in two steps (see scheme). Simple work‐up and convenient use in automated parallel synthesis are important features of this polymer‐bound reagent.