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N‐Substituted Corroles: A Novel Class of Chiral Ligands
Author(s) -
Gross Zeev,
Galili Nitsa
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990816)38:16<2366::aid-anie2366>3.0.co;2-w
Subject(s) - corrole , enantiomer , zinc , chemistry , combinatorial chemistry , stereochemistry , organic chemistry
Although known for almost 35 years , N‐substituted corroles have only now been recognized as being chiral. Several examples of these species were prepared in a facile two‐step synthesis and separated into their enantiomers by HPLC. The zinc( II ) complex of the corrole shown schematically was also synthesized.