Premium
Electronic Communication in C 4 ‐Bridged Binuclear Complexes with Paramagnetic Bisphosphane Manganese End Groups
Author(s) -
Kheradmandan Sohrab,
Heinze Katja,
Schmalle Helmut W.,
Berke Heinz
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990802)38:15<2270::aid-anie2270>3.0.co;2-6
Subject(s) - manganese , chain (unit) , paramagnetism , carbon chain , carbon fibers , polymer , conductivity , electron , electrical resistivity and conductivity , electron paramagnetic resonance , materials science , crystallography , chemistry , polymer chemistry , condensed matter physics , nuclear magnetic resonance , physics , organic chemistry , metallurgy , composite material , quantum mechanics , astronomy , composite number
Building blocks for conducting polymers or NLO materials are the linear, unsaturated carbon chain bridged manganese complexes 1 n + ( n =0–2). All oxidation states were investigated spectroscopically and by X‐ray structure determinations. The analytical data confirm a communication of the electrons over the C 4 chain—a prerequisite for electrical conductivity and NLO properties of oligo‐ or polymeric materials.