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New Types of Stable Aldehydes: Formylphosphane and Formylphosphane Oxide
Author(s) -
Amsallem Déborah,
Gornitzka Heinz,
Baceiredo Antoine,
Bertrand Guy
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990802)38:15<2201::aid-anie2201>3.0.co;2-e
Subject(s) - lone pair , reactivity (psychology) , chemistry , phosphorus , oxide , atom (system on chip) , stereochemistry , crystallography , organic chemistry , molecule , medicine , alternative medicine , pathology , computer science , embedded system
The reactivity of the formyl group in α ‐phosphorus‐substituted aldehydes 1 can be tuned by adjusting the coordination number of the phosphorus atom. When X is a lone pair, the formylphosphanes obtained are stable compounds, whereas when X=O a relatively unstable formylphosphane oxide is produced. R= i Pr 2 N, c Hex 2 N.