Premium
Demetalation of Tricarbonyl(cyclopentadienone)iron Complexes Initiated by a Ligand Exchange Reaction with NaOH—X‐Ray Analysis of a Complex with Nearly Square‐Planar Coordinated Sodium
Author(s) -
Knölker HansJoachim,
Baum Elke,
Goesmann Helmut,
Klauss Rüdiger
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990712)38:13/14<2064::aid-anie2064>3.0.co;2-w
Subject(s) - ligand (biochemistry) , chemistry , counterion , sodium , photochemistry , x ray , solid state , medicinal chemistry , inorganic chemistry , organic chemistry , ion , receptor , biochemistry , physics , quantum mechanics
A sequential exchange of one carbonyl ligand by a hydrido ligand with NaOH, and then by an iodo ligand with iodopentane and finally treatment with acid transforms tricarbonyl( η 4 ‐cyclopentadienone)iron complexes into dicarbonyl( η 5 ‐hydroxycyclopentadienyl)iodoiron complexes. These iodo complexes demetalate with high selectivity to the corresponding free ligands on contact with air in daylight. Under basic reaction conditions at the stage of the iodo complex an anionic dicarbonyl( η 4 ‐cyclopentadienone)iodoiron complex is generated, which is dimeric in the solid state and has an almost square‐planar arrangement of the ligands at the sodium counterion.