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A Three‐Dimensional Coordination Polymer with an Expanded NbO Structure
Author(s) -
Niu Tianyan,
Wang Xiqu,
Jacobson Allan J.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990712)38:13/14<1934::aid-anie1934>3.0.co;2-n
Subject(s) - natural bond orbital , molecule , coordination polymer , ion , acetonitrile , polymer , planar , crystallography , materials science , chemistry , organic chemistry , composite material , computer science , computer graphics (images)
The connection of square‐planar [Ni(CN) 4 ] 2− ions with Ph 3 Sn + ions results in 1 , a noninterpenetrated three‐dimensional coordination polymer with an expanded NbO structure. The (Ph 3 Sn) 2 Ni(CN) 4 framework (shown schematically without phenyl groups and solvent molecules) displays a large central cavity that is occupied by Ph 3 SnOH, acetonitrile, and water molecules.