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A Solution‐Phase Chemical Approach to a New Crystal Structure of Cobalt
Author(s) -
Dinega Dmitry P.,
Bawendi M. G.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990614)38:12<1788::aid-anie1788>3.0.co;2-2
Subject(s) - cobalt , thermal decomposition , crystal structure , metal , phase (matter) , oxide , decomposition , crystallography , crystal (programming language) , cobalt oxide , materials science , inorganic chemistry , crystal growth , ligand (biochemistry) , chemistry , chemical engineering , metallurgy , organic chemistry , computer science , receptor , biochemistry , programming language , engineering
Kinetic control of crystal growth in the presence of a coordinating ligand is critical for the formation of a new structure of elemental cobalt ( ε ‐cobalt, the unit cell with the two different types of cobalt atoms is shown), which was discovered upon analyzing the metallic powder produced by the thermal decomposition of [Co 2 (CO) 8 ] in solution in the presence of trioctylphosphane oxide [TOPO, Eq. (1)].