Premium
Manganese( III ) Formate: A Three‐Dimensional Framework That Traps Carbon Dioxide Molecules
Author(s) -
Cornia Andrea,
Caneschi Andrea,
Dapporto Paolo,
Fabretti Antonio C.,
Gatteschi Dante,
Malavasi Wanda,
Sangregorio Claudio,
Sessoli Roberta
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990614)38:12<1780::aid-anie1780>3.0.co;2-d
Subject(s) - formate , formic acid , molecule , manganese , permanganate , chemistry , inorganic chemistry , carbon dioxide , crystal structure , crystallography , photochemistry , organic chemistry , catalysis
Carbon dioxide, formic acid, and water molecules are trapped in the crystal lattice of manganese( III ) formate (see 1 ), which was obtained by reducing permanganate with formic acid. Each CO 2 guest molecule exhibits four C−H⋅⋅⋅O−C−O interactions with the three‐dimensional host framework of Mn(HCOO) 3 units. Compound 1 undergoes an antiferromagnetic phase transition at 27 K.