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Mixed Crossed Aldol Condensation between Conjugated Esters and Aldehydes Using Aluminum Tris(2,6‐diphenylphenoxide)
Author(s) -
Saito Susumu,
Shiozawa Masahito,
Yamamoto Hisashi
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990614)38:12<1769::aid-anie1769>3.0.co;2-0
Subject(s) - aldol condensation , tris , conjugated system , chemistry , condensation , lithium (medication) , aldol reaction , aluminium , condensation reaction , aldehyde , polymer chemistry , organic chemistry , catalysis , polymer , thermodynamics , endocrinology , medicine , biochemistry , physics
The combined use of aluminum tris(2,6‐diphenylphenoxide) (ATPH) and lithium 2,2,6,6‐tetramethylpiperidide (LTMP) has proven to be effective for the mixed crossed aldol condensation between conjugated esters and various aldehydes. An example is shown in Equation (1).