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A New Route to Organic Intercalates Consisting of Vanadium Pentoxide and Pyridines: (4‐H 2 N‐C 5 H 5 NH)V 2 O 5
Author(s) -
Shan Yongkui,
Huang Rui H.,
Huang Songping D.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990614)38:12<1751::aid-anie1751>3.0.co;2-d
Subject(s) - pentoxide , vanadium , intercalation (chemistry) , materials science , inorganic chemistry , chemistry , metallurgy
Light at the end of the tunnel! Intercalates of pyridine and layered inorganic compounds have intrigued chemists for at least two decades, but their structure determination has always been difficult owing to a lack of suitable single crystals. The intercalate (4‐H 2 N‐C 5 H 5 NH)V 2 O 5 has now been characterized by X‐ray crystal structure analysis, and its electronic structure and magnetic properties have been studied in detail.