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A Polycationic Metallodendrimer with 24 [Fe( η 5 ‐C 5 Me 5 )( η 6 ‐ N ‐Alkylaniline)] + Termini That Recognizes Chloride and Bromide Anions
Author(s) -
Valério Christine,
Alonso Ester,
Ruiz Jaime,
Blais JeanClaude,
Astruc Didier
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990614)38:12<1747::aid-anie1747>3.0.co;2-g
Subject(s) - dendrimer , ferrocene , bromide , chemistry , chloride , stereochemistry , crystallography , polymer chemistry , topology (electrical circuits) , combinatorial chemistry , organic chemistry , electrochemistry , electrode , mathematics , combinatorics
Pronounced dendritic effects are shown by the title compound 1 in the recognition of Cl − and Br − —this is shown by the comparison with a mononuclear compound with one dendrimer arm and a trinuclear compound with a tripodal dendrimer branch. Thus, 1 differs distinctly from 24‐ferrocene dendrimers of comparable topology.