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Tuning Dihydrogen Bonds: Enhanced Solid‐State Reactivity in a Dihydrogen‐Bonded System with Exceptionally Short H⋅⋅⋅H Distances
Author(s) -
Custelcean Radu,
Jackson James E.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990601)38:11<1661::aid-anie1661>3.0.co;2-o
Subject(s) - triethanolamine , reactivity (psychology) , covalent bond , solid state , hydrogen bond , crystallography , chemistry , ion , materials science , inorganic chemistry , organic chemistry , molecule , analytical chemistry (journal) , medicine , alternative medicine , pathology
Topochemical assembly of a covalent material can be achieved with the complex LiBH 4 ⋅TEA (TEA=triethanolamine; section of structure shown), a dihydrogen‐bonded system which has very short H⋅⋅⋅H contacts and high solid‐state reactivity due to acidity enhancement in the OH groups by Li + ion complexation.