Premium
Formation of Novel Dinuclear Mixed‐Valence Rhodium Complexes by Intramolecular Migration of a Chelating Ligand
Author(s) -
Herber Ulrich,
Weberndörfer Birgit,
Werner Helmut
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990601)38:11<1609::aid-anie1609>3.0.co;2-p
Subject(s) - rhodium , intramolecular force , chelation , chemistry , valence (chemistry) , ligand (biochemistry) , stereochemistry , organic chemistry , receptor , catalysis , biochemistry
Significantly different coordination spheres are displayed by the two central atoms of 2 , the first representative of a novel type of mixed‐valence dinuclear Rh 0 –Rh II compound, which was synthesized from the stibane‐bridged complex 1 . The Rh−Rh distance determined by an X‐ray crystal structure analysis of 2 indicates a metal–metal interaction between the two metal centers.