Premium
A Belted Monofacial Ionophore Featuring High Selectivity for Lithium Ion Complexation
Author(s) -
Paquette Leo A.,
Tae Jinsung,
Hickey Eugene R.,
Rogers Robin D.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990517)38:10<1409::aid-anie1409>3.0.co;2-u
Subject(s) - ionophore , selectivity , lithium (medication) , ion , chemistry , calcium , organic chemistry , medicine , catalysis
Despite its preferred equatorial conformation in the solid state and in solution, the cis , cis ‐trispiro ether 1 binds readily and strongly to lithium ions. The 2:1 sandwich complex 2 is initially formed and transformed progressively into the 1:1 species 3 upon the addition of more LiClO 4 .