Spacer Control of Directionality in Supramolecular Helicates Using an Inexpensive Approach | Zendy

Han Michael J. | Zendy; Bunce Siona | Zendy; Clarke Adam J. | Zendy; Alcock Nathaniel W. | Zendy

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Spacer Control of Directionality in Supramolecular Helicates Using an Inexpensive Approach

Author(s) -

Han Michael J.,

Bunce Siona,

Clarke Adam J.,

Alcock Nathaniel W.

Publication year - 1999

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/(sici)1521-3773(19990503)38:9<1277::aid-anie1277>3.0.co;2-d

Subject(s) - directionality , supramolecular chemistry , solid state , crystallography , helix (gastropod) , chemistry , materials science , stereochemistry , biology , crystal structure , ecology , genetics , snail

Careful selection of the spacer group used to separate the metal‐binding domains allows control of the directionality in a helix; self‐assembly leads uniquely to a double‐helical cation with a head‐to‐tail (HT) configuration (shown schematically) in both the solid state and solution.

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