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A Diazoalkane Derivative of a Polyoxometalate: Preparation and Structure of [Mo 6 O 18 (NNC(C 6 H 4 OCH 3 )CH 3 )] 2−
Author(s) -
Kwen Haidoo,
Young, Jr. Victor G.,
Maatta Eric A.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990419)38:8<1145::aid-anie1145>3.0.co;2-m
Subject(s) - polyoxometalate , chemistry , derivative (finance) , combinatorial chemistry , stereochemistry , organic chemistry , catalysis , business , finance
A new metathetical route to diazoalkane complexes is described which allows the introduction of such ligands into previously inaccessible environments. The method, which involves the exchange of oxo and [N 2 CR 2 ] ligands, is illustrated by the preparation of the first diazoalkane–polyoxometalate complex 1 .