Premium
Hexasupersilyl‐ triprismo ‐hexastannane ( t Bu 3 Si) 6 Sn 6 —The First Molecular Tin Compound Containing a Sn 6 Prism
Author(s) -
Wiberg Nils,
Lerner HansWolfram,
Nöth Heinrich,
Ponikwar Werner
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990419)38:8<1103::aid-anie1103>3.0.co;2-5
Subject(s) - tin , prism , trigonal crystal system , chemistry , crystallography , materials science , stereochemistry , optics , physics , crystal structure , organic chemistry
Dark violet hexastannane ( t Bu 3 Si) 6 Sn 6 displays a new framework motif for molecular tin compounds, in which six Sn atoms are located at the corners of a trigonal prism. The compound can be synthesized according to Equation (a). R*=Si t Bu 3 .