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Solvothermal Synthesis of the Canted Antiferromagnet {K 2 [CoO 3 PCH 2 N(CH 2 CO 2 ) 2 ]} 6 ⋅ x H 2 O
Author(s) -
Gutschke Siegfried O. H.,
Price Daniel J.,
Powell Annie K.,
Wood Paul T.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990419)38:8<1088::aid-anie1088>3.0.co;2-2
Subject(s) - antiferromagnetism , phosphonate , solvothermal synthesis , crystallography , carboxylate , cobalt , magnetization , materials science , condensed matter physics , stereochemistry , chemistry , organic chemistry , physics , metallurgy , quantum mechanics , magnetic field
A rare example of a molecular species prepared by solvothermal synthesis is the macrocyclic cobalt phosphonate/carboxylate 1 , whose structure is shown schematically. At low temperatures this compound displays spontaneous magnetization due to canted antiferromagnetic ordering, which is very unusual for a discrete molecular material.