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Design of New Mesogenic Block Molecules: Formation of Columnar Mesophases by Calamitic Bolaamphiphiles with Lateral Lipophilic Substituents
Author(s) -
Kölbel Marius,
Beyersdorff Tom,
Sletvold Ingrid,
Tschierske Carsten,
Kain Jens,
Diele Siegmar
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990419)38:8<1077::aid-anie1077>3.0.co;2-a
Subject(s) - mesogen , alkyl , liquid crystal , molecule , crystallography , materials science , stereochemistry , chemistry , liquid crystalline , organic chemistry , optoelectronics
Rigid bolaamphiphiles with lateral alkyl chains such as 1 form columnar mesophases of a novel type based on microsegregation of the three incompatible parts of the molecules (shown schematically).