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Coordination‐Ionspray‐MS (CIS‐MS), a Universal Detection and Characterization Method for Direct Coupling with Separation Techniques
Author(s) -
Bayer Ernst,
Gfrörer Petra,
Rentel Claus
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990401)38:7<992::aid-anie992>3.0.co;2-k
Subject(s) - chemistry , analyte , coupling (piping) , characterization (materials science) , combinatorial chemistry , terpene , mass spectrometry , chromatography , organic chemistry , nanotechnology , materials science , metallurgy
By on‐line addition of a central atom (for example, Ag I , B III , Pd II , Li I ) positively or negatively charged complexes of analytes can be formed for CIS‐MS. This technique is applicable to both polar and nonpolar compounds—for example, for alcohols, ethers, and a large number of olefins, polyolefins, and arenes as well as steroids, vitamins of the D and E families, carotinoids, polystyrols, terpenes, and unsaturated fatty acids—and can be readily coupled with separation techniques.