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A Potassium Complex of a Fluorine‐Containing Macrocyclic Cage Compound: Interactions between Fluorine Atoms and Metal Ions
Author(s) -
Takemura Hiroyuki,
Kon Noriyoshi,
Yasutake Mikio,
Kariyazono Hiroyuki,
Shinmyozu Teruo,
Inazu Takahiko
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990401)38:7<959::aid-anie959>3.0.co;2-8
Subject(s) - fluorine , chemistry , octahedron , cage , ion , crystallography , metal , inorganic chemistry , potassium , crystal structure , organic chemistry , mathematics , combinatorics
A new donor , the C−F unit, can be added to the field of host–guest chemistry. The interaction between fluorine atoms and a potassium ion was proven with the fluorine‐containing cage compound 1 as a host. The six fluorine atoms of K + ⊂ 1 are coordinated to K + in a distorted octahedral fashion.