Premium
The Carbonyl Chlorine( I ) Cation [ClCO] +
Author(s) -
Bernhardt Eduard,
Willner Helge,
Aubke Friedhelm
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990315)38:6<823::aid-anie823>3.0.co;2-2
Subject(s) - halogen , chlorine , chemistry , ion , gas phase , suspension (topology) , photochemistry , chlorine atom , polymer chemistry , inorganic chemistry , medicinal chemistry , computational chemistry , organic chemistry , alkyl , mathematics , homotopy , pure mathematics
The first carbonyl halogen cation in the condensed phase , the superelectrophilic [ClCO] + ion, has been clearly and unambiguously established by its complete, fully assigned vibrational spectrum. The cation is obtained by the reaction of COCl 2 with SbF 5 at room temperature in the form of a suspension, in which it is stabilized by oligomeric fluoroantimonate ions.