Premium
[{MeAl( μ 2 ‐F)} 2 N(2,6‐ i Pr 2 C 6 H 3 )] 4 — A Molecular Al‐F‐N Cage Compound
Author(s) -
Wessel Helge,
Park HyungSuh,
Müller Peter,
Roesky Herbert W.,
Usón Isabel
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990315)38:6<813::aid-anie813>3.0.co;2-6
Subject(s) - cage , ternary operation , chemistry , methane , stereochemistry , crystallography , mathematics , organic chemistry , combinatorics , computer science , programming language
In a two‐step elimination reaction the molecular Al‐F‐N cage compound 1 is synthesized from (2,6‐ i Pr 2 C 6 H 3 )NH 2 (ArNH 2 ) and Me 2 AlF under methane evolution. Compound 1 was characterized by means of X‐ray structure analysis and can be regarded as a precursor for ternary Al‐F‐N systems.