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BDH‐TTP as a Structural Isomer of BEDT‐TTF, and Its Two‐Dimensional Hexafluorophosphate Salt
Author(s) -
Yamada Junichi,
Watanabe Maki,
Anzai Hiroyuki,
Nishikawa Hiroyuki,
Ikemoto Isao,
Kikuchi Koichi
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990315)38:6<810::aid-anie810>3.0.co;2-i
Subject(s) - hexafluorophosphate , salt (chemistry) , chemistry , stereochemistry , crystallography , organic chemistry , ionic liquid , catalysis
Metallic behavior down to low temperature is shown by charge transfer salts of BDH‐TTP ( 1 ), a structural isomer of bis(ethylenedithio)tetrathiafulvalene (BEDT‐TTF). In the case of (BDH‐TTP) 2 PF 6 this behavior is attributed to the structure, which is made up of κ ‐type sheets of BDH‐TTP donor molecules and sheets of PF 6 − anions.