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Metal Complexes Bearing Terminal Borylene Ligands
Author(s) -
Wrackmeyer Bernd
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990315)38:6<771::aid-anie771>3.0.co;2-v
Subject(s) - chemistry , alkyl , aryl , metal , boron , terminal (telecommunication) , stereochemistry , polymer chemistry , organic chemistry , telecommunications , computer science
More and more metal complexes with terminal borylene ligands will be synthesized. Although these ligands in metal complexes must be stabilized either by integration of the boron atom into a polyhedral skeleton ( 1 ) or by B–N π interactions with a bulky amino group ( 2 ), the route to new complexes with terminal RB ligands (R=alkyl, aryl) is clearly indicated.