Biphasic Synthesis of Hydrogen Peroxide from Carbon Monoxide, Water, and Oxygen Catalyzed by Palladium Complexes with Bidentate Nitrogen Ligands | Zendy

Bianchi Daniele | Zendy; Bortolo Rossella | Zendy; D'Aloisio Rino | Zendy; Ricci Marco | Zendy

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Biphasic Synthesis of Hydrogen Peroxide from Carbon Monoxide, Water, and Oxygen Catalyzed by Palladium Complexes with Bidentate Nitrogen Ligands

Author(s) -

Bianchi Daniele,

Bortolo Rossella,

D'Aloisio Rino,

Ricci Marco

Publication year - 1999

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/(sici)1521-3773(19990301)38:5<706::aid-anie706>3.0.co;2-g

Subject(s) - chemistry , carbon monoxide , palladium , catalysis , hydrogen peroxide , denticity , oxygen , inorganic chemistry , ligand (biochemistry) , nitrogen , hydrogen , organic chemistry , crystal structure , receptor , biochemistry

Effective and stable Pd catalysts for the biphasic synthesis of hydrogen peroxide from carbon monoxide, oxygen, and water [Eq. (a)] can be obtained by the right choice of bidentate nitrogen ligand. The best turnover numbers (578) for this reaction have been achieved with palladium complexes with 2,9‐dimethyl‐4,7‐diphenyl‐1,10‐phenanthroline ligands.

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