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Biphasic Synthesis of Hydrogen Peroxide from Carbon Monoxide, Water, and Oxygen Catalyzed by Palladium Complexes with Bidentate Nitrogen Ligands
Author(s) -
Bianchi Daniele,
Bortolo Rossella,
D'Aloisio Rino,
Ricci Marco
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990301)38:5<706::aid-anie706>3.0.co;2-g
Subject(s) - chemistry , carbon monoxide , palladium , catalysis , hydrogen peroxide , denticity , oxygen , inorganic chemistry , ligand (biochemistry) , nitrogen , hydrogen , organic chemistry , crystal structure , receptor , biochemistry
Abstract Effective and stable Pd catalysts for the biphasic synthesis of hydrogen peroxide from carbon monoxide, oxygen, and water [Eq. (a)] can be obtained by the right choice of bidentate nitrogen ligand. The best turnover numbers (578) for this reaction have been achieved with palladium complexes with 2,9‐dimethyl‐4,7‐diphenyl‐1,10‐phenanthroline ligands.