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Crystal Engineering of Acentric Diamondoid Metal–Organic Coordination Networks
Author(s) -
Evans Owen R.,
Xiong RenGen,
Wang Zhiyong,
Wong George K.,
Lin Wenbin
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990215)38:4<536::aid-anie536>3.0.co;2-3
Subject(s) - diamondoid , acentric factor , thermal stability , zinc , materials science , cadmium , crystal structure , metal , crystal (programming language) , crystallography , chemistry , organic chemistry , molecule , metallurgy , computer science , programming language
Acentric three‐dimensional coordination polymers bis(isonicotinato)zinc ( 1 ) and bis(4‐pyridylacrylato)cadmium⋅H 2 O ( 2 ) were synthesized under hydro(solvo)thermal conditions; they exhibit a threefold (see picture) and fivefold diamondoid structure, respectively. Both 1 and 2 are active for second harmonic generation and exhibit remarkable thermal stability.