Premium
Kinetics and Mechanisms of the Reactions of π‐Allylpalladium Complexes with Nucleophiles
Author(s) -
Kuhn Oliver,
Mayr Herbert
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990201)38:3<343::aid-anie343>3.0.co;2-x
Subject(s) - nucleophile , electrophile , kinetics , chemistry , ligand (biochemistry) , kinetic energy , medicinal chemistry , computational chemistry , organic chemistry , catalysis , physics , biochemistry , receptor , quantum mechanics
Which nucleophiles are capable of attacking the allyl ligand of the Pd‐stabilized allyl cation 1 ? This question is answered by the electrophilicity parameter of 1 which is derived from kinetic investigations.