Premium
Cation‐Dependent Formation of Superstructures by One‐Pot Self‐Organization of Hydrogen‐Bonded Nickel Complexes
Author(s) -
Tadokoro Makoto,
Isobe Kiyoshi,
Uekusa Hidehiro,
Ohashi Yuji,
Toyoda Jiro,
Tashiro Koji,
Nakasuji Kazuhiro
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990115)38:1/2<95::aid-anie95>3.0.co;2-c
Subject(s) - nickel , hydrogen bond , acceptor , chemistry , hydrogen , tris , crystallography , inorganic chemistry , combinatorial chemistry , molecule , organic chemistry , physics , biochemistry , condensed matter physics
Four different types of molecular arrangements can be formed by one‐pot synthesis, depending on the type of counter cation used, when a new anionic tris(biimidazolato)nickel( II ) complex is used to form a network held together by hydrogen bonds. The connections occur through biimidazolate ligands, which can act as hydrogen bond donor as well as acceptor (see scheme).