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Oxidations of C−H and O−H Bonds by Isolated Copper( III ) Complexes
Author(s) -
Lockwood Mark A.,
Blubaugh Teresa J.,
Collier Andrea M.,
Lovell Scott,
Mayer James M.
Publication year - 1999
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/(sici)1521-3773(19990115)38:1/2<225::aid-anie225>3.0.co;2-u
Subject(s) - copper , oxime , anthracene , imine , chemistry , medicinal chemistry , stereochemistry , polymer chemistry , photochemistry , organic chemistry , catalysis
In oxidations by copper enzymes , copper( III ) species are increasingly being proposed as intermediates. A good model for such reactions is the oxidation of dihydroanthracene to anthracene by an isolated copper( III ) imine/oxime complex [Eq. (1)].